The saturation pressure of alpha-methyl benzyl alcohol (358 to 398) K and n-butyl formate (313 to 359) K was measured by an ebulliometric method. The vapor-liquid equilibrium (p, T, x, y) at (353.15, 373.15, and 393.15) K was measured by the ebulliometric method for the systems phenol + alpha-methyl benzyl alcohol and at (333.15, 343.15, and 353.15) K for 2-ethoxyethanol + n-butyl formate. The experimental vapor pressures were correlated with the Antoine and AEOS equations, whereas VLE was correlated with AEOS equation of state.