Journal of Applied Electrochemistry, Vol.25, No.1, 68-72, 1995
Impedance Spectroscopy Study with H-Doped Ammonium Uranylphosphate Self Supported Membranes
Equivalent circuit and electrical parameters for H-doped NH4UO2PO4.3H2O self supported membranes have been determined by impedance spectroscopy. The measurements were carried out with a dry membrane, at different temperatures, and a wet membrane in contact with different electrolyte solutions. Resistance values for the dry membrane decrease with temperature increase, which agrees with the weak protonic character of the H-doped ammonium uranylphosphate. On the other hand, differences in the electrical parameters, depending on the electrolyte considered were also obtained and are attributed to different conduction mechanisms.
Keywords:METAL URANYL PHOSPHATES