The ES-SAGD process was developed to improve the energy and oil drainage efficiency of the SAGD process. The idea of the ES-SAGD process is to co-inject solvent with steam and the co-injected solvent mixes with the bitumen to further reduce the viscosity of the heated bitumen along the boundary of the steam chamber thus enhances the oil recovery. Practically, the co-injected solvent will be a solvent mixture (such as diluent /naphtha) because of its availability and reduced cost than a pure hydrocarbon. This paper reports the results of an ES-SAGD lab test conducted with steam and diluent co-injection using Athabasca bitumen, To simulate the ES-SAGD test, a pseudo-component scheme to represent the complex solvent mixture in the numerical model is derived, based on the diluent composition and measured PVT data. The behaviours and effects of the co-injected solvent in the ES-SAGD process are analyzed through detailed history matching of the ES-SAGD test. Numerical sensitivity analyses are also performed to investigate the effects of some key parameters in the numerical approach.