화학공학소재연구정보센터
Journal of Canadian Petroleum Technology, Vol.46, No.8, 48-54, 2007
Laboratory testing of novel sealant for leaky wells
Many abandoned gas wells in western Canada leak gas to the surface. This paper presents the results of an experimental study to determine the possibility of using an asphalt-in-water emulsion as an efficient sealant for these abandoned leaky wells. A second application of this process would be to hinder the water flow from water producing formations. The asphalt-in-water emulsion used in the experiments had asphalt particles with an average particle size of around 4 gm and a 60% internal phase concentration. The emulsion exhibited a pseudo-plastic behaviour. Its viscosity ranged from 60 mPa.s at a shear rate of 60 RPM to 145 mPa.s at a shear rate of 6 RPM. The emulsion was found to be stable, even though it settled with time. Its original properties were retained after agitation and settling had occurred. Core flow experiments were performed in order to simulate injection in the near-wellbore region. The cores were prepared using silica sand with a 60 to 80 mesh size. The resulting cores had a porosity range of 25 to 32% and a permeability range of 2.5 to 9 Darcy. Experiments were performed under varying injection pressure conditions. In each case, solid plugs were formed and their length in the porous medium increased as a function of the injection pressure. In order to extend the length of the plugs, several anionic surfactants were tested as pre-flush solutions for conditioning the surface of the sand grains. This resulted in increasing the emulsion penetration into the cores. The basic mechanism of the process is to pressure up the emulsion next to a formation, forcing the emulsified asphalt to enter the porous medium and to form a flexible sealing plug. We surmise that the plug is formed through a combination of two pore blocking mechanisms: one by blocking the pores by the larger-than-pore droplets, and the other by adsorbing onto the sand grain surfaces. The experimental results showed that an asphalt-in-water emulsion can be successfully used to seal gas or water production from a high permeability formation. The study concludes with recommendations for further research required to implement the process in conventional or tight gas formations.