화학공학소재연구정보센터
Journal of Canadian Petroleum Technology, Vol.46, No.8, 34-41, 2007
Effect of H2S and pressure depletion on the CO2 MMP of Zama oils
Phase behaviour and minimum miscibility pressure measurements were carried out to evaluate the potential of applying miscible CO2/H2S flooding in the Zama reefs of NE Alberta, Canada. Since there is some variability in the properties of oils from different wells or reefs, the measurements were carried out on recombined reservoir fluids from two different wells. The injection solvent will be supplied from a nearby gas plant that is expected to produce CO2/H2S streams with a range of compositions due to a number of operational factors. Accordingly, three solvent injection gases were considered: pure CO2 and CO2 containing 20 and 40 mol% H2S. Minimum miscibility pressure (MMP) measurements were carried out using the rising bubble apparatus (RBA). The NIMP decreased almost linearly with the amount of H2S in the injection gas in the range of compositions studied. Some evidence of precipitation of solids was observed. Measurements were also carried out to determine the CO2 MMP of these reservoir fluids as they were depleted of gas through a differential liberation procedure. The results show that the NIMP decreased with decreasing liberation pressure. Key properties of the liberated reservoir fluids were also measured and compared with those of the recombined reservoir fluids. The results show that miscible flooding with sour acid gas is feasible in this case, and could provide an excellent means of storing/sequestering these gases while improving oil recovery.