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Journal of Canadian Petroleum Technology, Vol.44, No.3, 54-61, 2005
Low-temperature oxidation of oils in terms of SARA fractions: Why simple reaction models don't work
The low-temperature oxidation (LTO) reactions of the SARA fractions separated from two crude oils were studied in the presence of their reservoir sands at temperatures between 130 and 230 degrees C. The results indicated that the usual approach to modelling LTO-the use of a very few single-step Arrhenius-rate equations-could not be made to reflect the observed reaction kinetics. Instead, this investigation found that the following reaction characteristics were needed for accurate reaction modelling: 1) a change in the order of reaction with respect to oxygen concentration from 1/2 to 1 as temperature rises; 2) the repression of a saturates oxidation reaction by other fractions; and, 3) a prominent induction period exhibited by the saturates fraction. The compositions and yields of the ultimate LTO reaction products were measured, and these included relatively stable residues with high oxygen contents. Because the LTO reactions play an important role in enhanced oil recovery by air injection methods, the above information is valuable for the simulation and prediction of these processes.