Journal of Applied Electrochemistry, Vol.24, No.6, 481-488, 1994
Dynamic Analysis of Charge-Transport in Fluidized-Bed Electrodes - Impedance Techniques for Electroactive Beds
Impedance techniques are used to investigate the average dynamic behaviour of a fluidized bed of gold-coated beads in potassium ferri-ferrocyanide/NaOH solution. A transmission line is used as a model. The main features of the fluidized bed are correctly interpreted, especially the capacitive high frequency impedance related to the intermittent contacts between the particles. The use of a non-uniform transmission line is attempted in order to study the influence of a distance dependent charge transfer mechanism in the bulk of the fluidized bed.
Keywords:ELECTROCHEMICAL-BEHAVIOR