At a molecular level adhesive joint strength of pressure-sensitive adhesives (PSAs) is governed by the ratio between two generally conflicting factors: high energy of cohesive molecular interactions and large free volume. Increase in temperature leads to domination of the free volume contribution over the cohesive strength, affecting mechanisms of the debonding process, examined with a probe tack test. Linear viscoelastic properties and probe tack adhesion of five types of PSAs have been studied: polyisobutylene (PIB); acrylic, styrene-isoprene-styrene (SIS) triblock copolymer; hydrogen-bonded complex of high molecular weight poly(N-vinyl pyrrolidone), PVP; with oligomeric poly(ethylene glycol), PEG; and plasticized poly-base-polyacid polyelectrolyte complex (PEC). The transition from solid-like mechanism of debonding to ductile type of adhesive bond failure with fibrillation of adhesive layer has been established to occur for all examined PSAs under temperature increase within the range from -20 to 80 degrees C. The Dahlquist criterion of tack, which defines the value of the storage modulus, G', below 0.1 MPa, featured for all the PSAs demonstrating maximum work of debonding, has been found to have a universal character and holds at corresponding temperatures for all the PSAs examined, including both typical and innovative adhesives. In addition to this adhesion predictor we have also established that for all the PSAs the transition from a solid-like debonding mechanism to a ductile type of debonding is observed in the range of G' = 0.09-0.34 MPa. The value of the dissipation factor, tan delta, is also included in the analysis of correlation between linear viscoelasticity and probe tack behavior.