The Permian age coal seams in the Candiota Coalfield represent the largest coal deposit of the country. Currently two seams are mined, called "Camada Candiota Superior" and "Camada Candiota Inferior". The other coal seams of the coalfield, seams S1-S9 (upper seams) and 11-15 (lower seams) have as yet not been exploited. The objective of this paper is to perform a detailed sequence stratigraphic, petrologic and chemical study of the upper and lower coal seams, thereby generating data for assisting in the development and better use of the coal-bearing interval. The methodology includes application of the concepts of sequence stratigraphy, which includes the lithological interpretation of the core to establish the depositional environments and genetic correlation between facies associations to define parasequences and bounding surfaces; coal petrology (analysis of the reflectance of vitrinite, determination of the petrographic composition of the coals by maceral analyses), and chemical analyses such as sulphur determination, proximate analyses (ash, moisture, volatile matter, and fixed carbon), and elemental analyses. Three main depositional systems were so far identified: alluvial fan, fluvial system, lagoonal estuary system. This study shows that coal development was controlled by accommodation/accumulation rates, with coal seams with greater thickness and lateral continuity being formed within the transgressive systems tract (lagoonal depositional system) of parasequence 2 (PS2), indicating that the accumulation rates of the peat and distribution of the coal seams were controlled by stratigraphic setting. Vitrinite reflectances for the upper and lower coal seams are indicative of subbituminous rank (Rrandom = 0.36-0.47%), with evidence that anomalously low reflectance values are related to high mineral-matter contents. Maceral composition is highly variable, with some coal seams being extremely rich in inertinite (up to 65 vol.%). The upper and lower coal seams are ash-rich, ranging from 22.4 to 62.3 wt.%, with the majority being classified as carbonaceous rocks very low grade coal. Sulphur contents in the upper and lower seams range from 0.41 to 8.08 wt.%, with the majority below 1 wt.%. The high amounts of sulphur (>3 wt.%) in some of the coal seams may indicate coastal flooding during the lifetime of the mire or shortly after. (C) 2010 Elsevier B.V. All rights reserved.