Attenuated total reflectance micro-Fourier transform infrared (ATR-FTIR) spectrometry has been successfully used to characterise coal macerals, in particular telocollinite, and to investigate changes in the aromatic and aliphatic functional groups in the telocollinite, over a wide rank range (Rv(max) from 0.39 to 3.52%) in coals from the Bowen Basin, Queensland, Australia. The results show that ATR-FTIR is very sensitive to the increasing aromaticity (the fraction of carbon atoms involved in aromatic units) of the telocollinites, and thus is a very useful toot to study the evolution of aromatic and aliphatic functional groups with maturation of telocollinite. and also to differentiate and characterise the various macerals in coal samples. In comparison with other micro-FTIR techniques, ATR-FTIR has many advantages: (1) no difficult and time-consuming procedures are required to obtain "pure" maceral separations, or for preparation of thin coal slices; (2) the ATR-FTIR spectra have better signal-to-noise ratio and increased sensitivity; (3) the ATR-FTIR spectra are similar to absorption spectra, but without significant spectral distortion. (c) 2006 Elsevier B.V. All rights reserved.