화학공학소재연구정보센터
Journal of Adhesion Science and Technology, Vol.12, No.10, 1071-1080, 1998
Effect of interfacial mixing by N+ implantation on the adhesion and friction of Ti film on Si3N4
A thin ion-plated Ti him on sintered Si3N4 was implanted with 110 keV N+ at doses of 1 x 10(16) to 3 x 10(17) ions cm(-2) and substrate temperature of 60 degrees C. The adhesion of the ion-plated Ti film and the N+-implanted films on Si3N4 was examined using a scratch tester and a scanning electron microscope. The interfacial chemistry of the N+-implanted Ti/Si3N4 Specimens was examined using sample tilting diffraction (STD), Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS), It was found that at a dose of 3 x 10(17) N+ cm-2, the critical load for the scratch test on the N+-implanted Ti film/Si3N4 substrate increased from 10.8 to 50.0 N; consequently, the implanted films were not easily removed by interfacial failure as in the case of the unimplanted one. AES indicated that N+ implantation produced substantial interfacial mixing and interfacial grading in the Ti/Si3N4 system. The STD and XPS analyses revealed that a TixN (x = 1, 2) compound was formed by N+ implantation, The combination of these effects in the N+- implanted Ti/Si3N4 specimen provided an increased adhesion that was approximately 4.6 times that of the unimplanted system. In addition, the hydrocarbon adsorbed in the near-surface region of Ti films reduced the adhesion component of friction between the metal and the N+-implanted specimen.