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(N-2)(3-) Radical Chemistry via Trivalent Lanthanide Salt/Alkali Metal Reduction of Dinitrogen: New Syntheses and Examples of (N-2)(2-) and (N-2)(3-) Complexes and Density Functional Theory Comparisons of Closed Shell Sc3+, Y3+, and Lu3+ versus 4f(9) Dy3+ Fang M, Bates JE, Lorenz SE, Lee DS, Rego DB, Ziller JW, Furche F, Evans WJ Inorganic Chemistry, 50(4), 1459, 2011 |
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Synthesis and Reactivity of Bis(tetramethylcyclopentadienyl) Yttrium Metallocenes Including the Reduction of Me3SiN3 to [(Me3Si)(2)N](-) with [(C5Me4H)(2)Y(THF)](2)(mu-eta(2):eta(2)-N-2) Lorenz SE, Schmiege BM, Lee DS, Ziller JW, Evans WJ Inorganic Chemistry, 49(14), 6655, 2010 |
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Synthesis, Structure, and Density Functional Theory Analysis of a Scandium Dinitrogen Complex, [(C5Me4H)(2)Sc](2)(mu-eta(2):eta(2)-N-2) Demir S, Lorenz SE, Fang M, Furche F, Meyer G, Ziller JW, Evans WJ Journal of the American Chemical Society, 132(32), 11151, 2010 |
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Investigating Metal Size Effects in the Ln(2)(mu-eta(2):eta(2)-N-2) Reduction System: Reductive Reactivity with Complexes of the Largest and Smallest Trivalent Lanthanide Ions, La3+ and Lu3+ Evans WJ, Lorenz SE, Ziller JW Inorganic Chemistry, 48(5), 2001, 2009 |
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Reductive reactivity of the organolanthanide hydrides, [(C5Me5)(2)LnH](x), leads to ansa-allyl cyclopentadienyl (eta(5)-C5Me4CH2-C5Me4CH2-eta(3))(2-) and trianionic cyclooctatetraenyl (C8H7)(3-) ligands Evans WJ, Schmiege BM, Lorenz SE, Miller KA, Champagne TM, Ziller JW, DiPasquale AG, Rheingold AL Journal of the American Chemical Society, 130(26), 8555, 2008 |