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1 Synthesis of Sterically Hindered Primary Amines by Concurrent Tandem Photoredox Catalysis
Nicastri MC, Lehnherr D, Lam YH, DiRocco DA, Rovis T
Journal of the American Chemical Society, 142(2), 987, 2020
2 Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer
Lehnherr D, Lam YH, Nicastri MC, Liu JC, Newman JA, Regalado EL, DiRocco DA, Rovis T
Journal of the American Chemical Society, 142(1), 468, 2020
3 Direct arylation of strong aliphatic C-H bonds
Perry IB, Brewer TF, Sarver PJ, Schultz DM, DiRocco DA, MacMillan DWC
Nature, 560(7716), 70, 2018
4 Mapping the dark space of chemical reactions with extended nanomole synthesis and MALDI-TOF MS
Lin SS, Dikler S, Blincoe WD, Ferguson RD, Sheridan RP, Peng ZW, Conway DV, Zawatzky K, Wang H, Cernak T, Davies IW, DiRocco DA, Sheng HM, Welch CJ, Dreher SD
Science, 361(6402), 569, 2018
5 Asymmetric Hydrogen Bonding Catalysis for the Synthesis of Dihydroquinazoline-Containing Antiviral, Letermovir
Chung CK, Liu ZJ, Lexa KW, Andreani T, Xu YJ, Ji YN, DiRocco DA, Humphrey GR, Ruck RT
Journal of the American Chemical Society, 139(31), 10637, 2017
6 A multifunctional catalyst that stereoselectively assembles prodrugs
DiRocco DA, Ji YN, Sherer EC, Klapars A, Reibarkh M, Dropinski J, Mathew R, Maligres P, Hyde AM, Limanto J, Brunskill A, Ruck RT, Campeau LC, Davies IW
Science, 356(6336), 426, 2017
7 Aryl amination using ligand-free Ni(II) salts and photoredox catalysis
Corcoran EB, Pirnot MT, Lin SS, Dreher SD, DiRocco DA, Davies IW, Buchwald SL, MacMillan DWC
Science, 353(6296), 279, 2016
8 Asymmetric N-Heterocyclic Carbene Catalyzed Addition of Enals to Nitroalkenes: Controlling Stereochemistry via the Homoenolate Reactivity Pathway To Access delta-Lactams
White NA, DiRocco DA, Rovis T
Journal of the American Chemical Society, 135(23), 8504, 2013
9 Isolable Analogues of the Breslow Intermediate Derived from Chiral Triazolylidene Carbenes
DiRocco DA, Oberg KM, Rovis T
Journal of the American Chemical Society, 134(14), 6143, 2012
10 Catalytic Asymmetric alpha-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis
DiRocco DA, Rovis T
Journal of the American Chemical Society, 134(19), 8094, 2012