화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 고분자구조 및 물성
제목 A Fast and Robust Way to Directed Self-Assembly of High-χ Block Copolymers via a Combined Treatment Comprising Solvothermal and Immersion Annealing
초록 Here, we provide a simple and fast methodology to induce morphological transition of poly(styrene-b-dimethylsiloxane) (PS-b-PDMS) BCPs via combined annealing method consisting of solvothermal and immersion annealing steps. Particularly, we place an emphasis on understanding how the above-mentioned combined annealing method affects directed self-assembly of high-χ PS-b-PDMS. We also found optimum morphological transition condition, showing well-defined nanostructures within short annealing time (< 10 min). Furthermore, we accomplish morphological transition of well-ordered 15 nm line and 20 nm dot structures during periodic combined annealing process. These results could extend to other BCPs, providing a guideline to effectively manipulate morphologies of nanostructures for the advanced patterning technology.
저자 변명환
소속 계명대
키워드 block copolymer; directed self-assembly; morphological transition; solvothermal annealing; immersion annealing
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