화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX)
권호 21권 2호, p.2473
발표분야 C1가스 전환 심포지엄: 화학적 방법(촉매부문위원회)
제목 Syngas conversion to useful petrochemicals using heterogeneous catalysts
초록 1, A new, green and general preparation method for bimodal catalysts is developed and applied in slurry-phase Fischer-Tropsch synthesis (FTS), exhibiting very high activity for diesel synthesis from syngas (CO+H2).
2, “Capsule catalyst” concept is invented by the author.  A capsule catalyst, with FTS catalyst as a core and H-type zeolite as a shell, can realize one-step synthesis of gasoline (iso-paraffin) from syngas.  This is completely different from the conventional FTS reactions producing only diesel.  This capsule catalyst concept can be applied in a lot of catalysis reactions or organic reactions such as dimethyl ether (DME) one-step synthesis or epoxide synthesis (ref. 1).
3, A new low-temperature methanol synthesis method (130-170oC, 50bar) is developed using only solid catalysts based on a new synthesis route via formate.  Initiated by this new technology, a new low-temperature DME synthesis method is also developed (ref. 2).
4, Graphene, carbon nanotube are also tuned as solid catalyst supports applied in syngas conversion to petrochemicals.
저자 Noritatsu Tsubaki
소속 Graduate School of Engineering
키워드 Fischer-Trospch synthesis; methanol synthesis; syngas; petrochemicals; zeolite.
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