| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.1015 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Synthesis of highly ordered mesoporous CeO2 and water-gas shift reaction over CuxCo3-xO4/ mesoporous CeO2 catalyst |
| 초록 |
We report on the low water-gas shift (WGS, CO + H2O →H2 + CO2) activity of CuxCo3-xO4 supported on highly ordered mesoporous ceria oxide with high surface area and a large pore volume. The preparation method was via a nano-replication method using a KIT-6 template to get highly ordered mesoporous CeO2 support, then loading CuxCo3-xO4 on the meso-CeO2 by an incipient wetness impregnation. The structure of the catalysts and the WGS reaction intermediate were characterized using powder X-ray diffraction (XRD), nitrogen sorption & adsorption isotherms, scanning electron microscopy (SEM), temperature programmed surface experiments. A 20 wt% CuxCo3-xO4/meso-CeO2 catalyst displayed the highest catalytic activity among all the prepared catalysts. Beside high activity, the 20 wt% CuxCo3-xO4/meso-CeO2 catalyst also exhibited the stability under WGS conditions compared to 20 wt% CuxCo3-xO4. |
| 저자 |
LI CHENGBIN, 이정화, 홍경희, Sivaranjani Kumarsrinivasan, 오화용, 조혜진, 김지만
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| 소속 |
성균관대 |
| 키워드 |
mesoporous metal oxide; Water gas shift
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| E-Mail |
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| 원문파일 |
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