화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_콜로이드·계면화학
제목 Controlled Synthesis and Catalytic Application of Dendritic Fibrous Nanosilica/Metallic Nanoparticles@Zinc-Based Coordination Polymer Hybrid Nanomaterials
초록 Dendritic fibrous nanosilica (DFNS) with high stability and permanent porosity is successfully employed as a template to fabricate DFNS/Au hybrid nanomaterials. For the controllable synthesis of secondary materials, the functionalization of the as-prepared DFNS/Au hybrids by amino groups –NH2 plays an essential role. The amine-functionalized DFNS/Au hybrids subsequently employed as seeds to grow zinc-based coordination polymer with [N3] ligand (Zn-CPN) via solvothermal process, and this leads to the formation of DFNS/Au@Zn-CPN core-shell hybrid nanomaterials. The obtained DFNS/Au@Zn-CPN hybrids exhibit enhanced catalytic performance for Knoevenagel condensation reaction.
저자 TRANMINHNGOC, 유효종
소속 한양대
키워드 DFNS; hybrid nanomaterial; Knoevenagel
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