화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2014년 가을 (11/12 ~ 11/14, 엑스코(대구))
권호 18권 2호
발표분야 고분자-포스터
제목 Synthesis and thermal insulation properties of polyurethane foams prepared with expandable microspheres
초록 Polyurethane foams (PUFs) are materials with low thermal conductivity due to the presence of a skeleton made of more or less regular open or closed cells. It has been known that the thermal conductivity of PUF depends on the foam density, cell size, cell orientation, and ratio of close to open cell content and on the thermal conductivity of the gases (blowing agent). In order to investigate thermal behavior of PUFs, PUFs structures such as cell density, cell size and cell shape are well controlled using expandable microspheres to expand 1-10 minutes at 140-180℃. In our study, several prepolymers such as PCL (Mn=300), PCL (Mn=530), PCL (Mn=900) and HTPB are used to find a proper PU matrix. The thermal conductivity behaviors of resulting PUFs are discussed with scientific principles and mechanism.    
저자 변여1, 정찬홍1, 권영환1, 김진석2
소속 1대구대, 2국방과학(연)
키워드 PU foam; insulation; expandable microsphere; thermal conductivity
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