| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
석유화학윤활유 |
| 제목 |
Catalytic properties of HZSM-5 zeolite on synthesis of acetyl triethyl citrate by acetylation of triethyl citrate with acetic anhydride |
| 초록 |
Acetyltriethylcitrate (ATEC) is an ester derived from citric acid, which can be used to replace phthalate esters as a nontoxic plasticizer. This paper presents a preparation method of ATEC by acetylation of triethylcitrate (TEC) with acetic anhydride on various acid catalysts. TEC was also prepared from citric acid monohydrate and ethanol to use as a raw material in the acetylation for the ATEC preparation. A methanesulphonic acid was employed as a homogeneous catalyst. HZSM-5 zeolites were also introduced as a heterogeneous catalyst. Catalytic activities of the acid catalysts were evaluated in comparison with yields of ATEC. The high conversion was obtained ca. 80% on HZ(75) zeolite. The yield of ATEC reached to ca. 96% on the zeolite catalyst. The mild acid strength of HZSM-5 zeolites led to high catalytic activity. |
| 저자 |
정상민, 정경환, 이원준, 이 헌, 정상철
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| 소속 |
순천대 |
| 키워드 |
acetyl triethylcitrate; citric acid; phthalate; plasticizer; acid catalyst
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| E-Mail |
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