화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 고분자 가공/복합재료
제목 Entrapping Organophosphorus Hydrolase in γ-Alumina Nanoparticles for Enzymatic Reaction
초록 Herein, we report on the synthesis of nanocatalyst including γ-alumina nanoparticles with good textural properties as a host matrix and organophosphorus hydrolase (OPH) as a guest material for the enzymatic reaction. After the immobilization of OPH on γ-aluminas, the structures of γ-alumina nanoparticles were conserved, as elucidated by TEM and XRD analysis. The physical properties of OPH-immobilized γ-alumina nanoparticles were characterized by TGA and gas sorption/desorption analysis. The as-obtained nanocatalyst exhibited higher catalytic performance compared to those of OPH-immobilized commercial aluminas, due to not good textural properties of γ-aluminas but also favorable interactions between the host and guest materials. Therefore, the OPH-immobilized γ-alumina nanoparticles serve as an advanced biocatalyst based on a host-guest system for the application in enzymatic reaction [This work was supported in part by MIC & IITA through IT Leading R&D Support Project.].
저자 최봉길1, 박호석2, 박태정2, 홍원희2, 이상엽2
소속 1한국과학기술원, 2한국과학기술원 / 생명화학공학과
키워드 γ-alumina; enxyme; ionic liquid; organophosphorus hydrolase
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