학회 |
한국고분자학회 |
학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
권호 |
33권 2호 |
발표분야 |
고분자 가공/복합재료 |
제목 |
Entrapping Organophosphorus Hydrolase in γ-Alumina Nanoparticles for Enzymatic Reaction |
초록 |
Herein, we report on the synthesis of nanocatalyst including γ-alumina nanoparticles with good textural properties as a host matrix and organophosphorus hydrolase (OPH) as a guest material for the enzymatic reaction. After the immobilization of OPH on γ-aluminas, the structures of γ-alumina nanoparticles were conserved, as elucidated by TEM and XRD analysis. The physical properties of OPH-immobilized γ-alumina nanoparticles were characterized by TGA and gas sorption/desorption analysis. The as-obtained nanocatalyst exhibited higher catalytic performance compared to those of OPH-immobilized commercial aluminas, due to not good textural properties of γ-aluminas but also favorable interactions between the host and guest materials. Therefore, the OPH-immobilized γ-alumina nanoparticles serve as an advanced biocatalyst based on a host-guest system for the application in enzymatic reaction [This work was supported in part by MIC & IITA through IT Leading R&D Support Project.]. |
저자 |
최봉길1, 박호석2, 박태정2, 홍원희2, 이상엽2
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소속 |
1한국과학기술원, 2한국과학기술원 / 생명화학공학과 |
키워드 |
γ-alumina; enxyme; ionic liquid; organophosphorus hydrolase
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E-Mail |
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