| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
나노_포스터 |
| 제목 |
Encapsulated Cobalt Oxide in 2D Conjugated Network Polymer as a Hydrogen Evolution Catalyst |
| 초록 |
In the hydrogen generation field, cobalt oxides have been regarded as promising catalysts, 2D network polymer-supported cobalt-oxide catalysts with good crystallinity are highly anticipated to enhance catalytic performance. Here we report the fabrication of a 2D nitrogenated network polymerencapsulated cobalt-oxide (Co@C2N) catalyst via an in situ solvothermal synthesis. Co@C2N exhibits outstanding catalytic activities for hydrogen (H2) generation from the hydrolysis of alkaline sodium borohydride (NaBH4) solutions. The rate of maximum hydrogen generation is comparable to the best reported values for catalysts containing other noble metals in alkaline solutions. Moreover, Co@C2N can also catalyze the in situ reduction of a nitro group into an amino group (4-nitrophenol to 4-aminophenol) in the presence of NaBH4. The origin of high catalytic activity with enhanced stability could be due to the strong interaction between the cobalt-oxide nanoparticle and the C2N framework, which contains a large portion of nitrogen. |
| 저자 |
백종범, 유정우, 박정민, 김석진, 정선민, Javeed Mahmood
|
| 소속 |
울산과학기술대 |
| 키워드 |
Cobalt Oxide; Encapsulation; Hydrogen Evolution; C2N
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| E-Mail |
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