화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 에너지저장·변환_포스터
제목 Investigation of unexpected phenomena during bromination reaction in the synthesis of anion exchange materials
초록 The most recent studies to produce anion exchange materials has greatly favored the bromination reaction, one of conventional methods for introducing cationic group. The main advantage of the bromination reaction is that it allows for a nearly quantitative conversion of precursors as well as fast reaction rates. However, various limitations of bromination reaction still existed such as unpredictable dibromination and chain scission. Accordingly, our research focused on overcoming the limitation of bromination reaction by controlling reaction conditions. Herein, a series of polymer containing a benzyl bromide group were synthesized using bromination reaction under various reaction condition. In particular, we measured a nuclear magnetic resonance (NMR) spectroscopy, gel permeation chromatography and physical properties of synthesized polymer.
저자 차민석1, 오성근2, 홍영택1, 이장용1
소속 1한국화학(연), 2한양대
키워드 anion exchange materials; bromination reaction
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