| 초록 |
The separation and recovery of rare earth elements (REEs) are critical to meet the ever-increasing demand for REEs extensively used in many high technology devices. For their efficient separation via adsorption, a stable adsorbent with a high adsorption capacity and fast adsorption kinetics is required. The poly(amidoamine) dendrimer (PAMAM) with a three-dimensional tree-like architecture possessing a large number of functional nitrogen and amino groups can serve as a chelating agent toward metal ions including REE ions. Herein, the second generation G2 PAMAM dendrimer-grafted KCC-1 structure was prepared and applied as an adsorbent for the recovery of gadolinium ion from aqueous medium. The adsorption behaviors of Gd3+ over the materials were examined in detail as a function of solution pH, initial concentration of Gd3+, and contact time. Finally, adsorption selectivity of Gd3+ in the presence of competing ions and the reusability of the adsorbents were also investigated. |
