화학공학소재연구정보센터
학회 한국재료학회
학술대회 2016년 봄 (05/18 ~ 05/20, 여수 디오션리조트 )
권호 22권 1호
발표분야 B. 나노화학/바이오 재료 분과
제목 Superhydrophobic surface using hierarchical self-assembly of bent-core liquid crystals
초록 There has been growing interest in self-assembled organic materials for many functional applications. In this study, we suggest banana-shaped liquid crystal (LC) phase as soft nano-building blocks to generate unique superstructure: helical nanofilaments (HNFs). Here, we suggest surface-induced alignment as one of the most effective and simple approach to control this complex nanostructure. Once initial molecular orientations are determined under given surface conditions, further assembling processes are followed even governing the final morphology of HNFs. We successfully prepared various kinds of interfacial conditions by using chemically- physically modified substrates, and these surface effects on the LC orientations are observed by various scattering (GIXD) and visualizing (SEM, POM) techniques. This study gives not only the important insight into LC-based self-assembly system for patterning application, but also the example generating hydrophobic surfaces.
저자 김한임1, 이선희1, 차윤정1, Ewa Korblova2, David M. Walba2, Noel. A. Clark2, Sang Bok Lee3, 윤동기1
소속 1KAIST, 2Univ. of Colorado, 3Univ. of Maryland
키워드 Helical nanofilaments; bent-core LCs; self-assembly; superhydrophobic surface
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