| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis and Characterization of Low Band Gap Small Molecules based on Fluorine Substituted Benzothiadiazole for Photovoltaic Application |
| 초록 |
We successfully designed D-π-A-π-D three small molecules, BTTP, BTTP-F, and BTTP-FF were synthesized and characterized in which benzothiadiazole as a electron acceptor (A), triphenylamine as a electron donor (D) and thiophene as a linker (π) between electron donor and electron acceptor. Fluorine was substituted in benzothiadiazole core to major the effect of photovoltaic properties. To understand the effect of fluorine substituted benzothiadiazole, we were fabricated the photovoltaic cell (PVCs) with inverted device structure ITO/ZnO/active layer/MoO3/Ag. In active layer, BTTP; BTTP-F; BTTP-FF used as electron donor and PC61BM also PC71BM used as electron acceptor and compared to get the highest power conversion efficiency (PCE). These three small molecules also showed low band gap which were beneficial for improvement of the open circuit voltage (Voc). In this research, the synthesis, optical, electrochemical properties, and their application of solar cells have been investigated. |
| 저자 |
Sella Kurnia Putri1, 김윤환2, 김주현2, 장동욱2
|
| 소속 |
1Pukyong National Univ., 2부경대 |
| 키워드 |
Benzothiadiazole; Fluorine; Photovoltaic; Solar Cell
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| E-Mail |
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