| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Optimum reaction conditions on Co/0.05P-Al2O3 Fischer-Tropsch catalyst by using statistical design of experiment (DOE) |
| 초록 |
The effect of reaction variables on Co/0.05P-Al2O3 Fischer-Tropsch catalyst was investigated by using the statistical design of experiment (DOE) method at fixed-bed reactor. The P modified Al2O3 support was synthesized by using the sol-gel method with the addition of phosphoric acid at P/Al mole ratio of 0.05 and 20wt.%Co/0.05P-Al2O3 was prepared by wet impregnation method. At SV = 2000 L/kgcat/h, the CO conversion and C5+ yield were maximized around 38.6% and 32.7% respectively at the following optimum reaction conditions; T = ~ 225 oC and P = ~ 22.8 bar. The statistical DOE method is useful method to find out the optimum reaction conditions with a minimum experimental run. |
| 저자 |
배종욱, 김승문, 오종혁, 전기원
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| 소속 |
한국화학(연) |
| 키워드 |
Fischer-Tropsch; syngas; cobalt; P modified Al2O3; design of experiment (DOE)
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| E-Mail |
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