화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 에너지저장변환
제목 A-D-A type small molecule acceptor based on new end-capping unit for Non-fullerene Polymer solar cells
초록 Polymer solar cells (PSCs) have drawn significant attention for these applications due to the global technology trends toward economic feasibility and continuous development coupled with efforts to preserve the environment. Fullerene and their derivatives have been used to electron-acceptor materials in PSCs. But they have some disadvantages, such as cost, stability and limited spectral absorption. To overcome their insufficiencies, we synthesized new small molecule accepter using caffeine derivatives. Caffeine can form intermolecular hydrogen bonding between N-H···O=C of the molecules. The effects of hydrogen bonding over extensive π–π stacking results in morphologies that lead to higher photovoltaic efficiencies. In this study, the synthesized molecules are characterized by 1H-NMR, TGA, UV-vis spectrometer, CV and fabricated device were measured.
저자 이예진, 전성재, 한용운, 문두경
소속 건국대
키워드 Organic photovoltaic; Bulk-heterojunction; Conjugated Polymer; Non-fullerene acceptor
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