화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 나노구조제어 및 분석기술
제목 Fabrication and Characterization of Photoluminescent Dyes/Poly(acrylonitrile) Coaxial Nanotubes
초록 Poly(acrylonitrile) (PAN) nanotubes with tunable wall thickness were successfully fabricated using a modified vapor deposition polymerization method. To enhance the wall uniformity of PAN nanotubes, heptane was employed as a non-reactive solvent. The heptane vapor in the reaction vessel plays an important role in producing the nanotube with tunable and uniform wall thickness. Moreover, photoluminescence dyes such as pyrene and rhodamine B were employed as host materials. These dyes were loaded into the inner surface of the PAN nanotubes and effectively encapsulated with a supplemental PAN layer. Confocal laser scanning microscopy images confirmed the successful fabrication of PAN-dye-PAN nanotubes without phase separation of the organic dyes. The photoluminescent analysis demonstrated the effective confinement of pyrene as well as rhodamine B in PAN layer with a varying concentration of dyes.
저자 민사훈, 이경진, 장정식
소속 서울대
키워드 Coaxial nanotubes; poly(acrylonitrile); dyes; FRET; vapor deposition polymerization
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