학회 | 한국화학공학회 |
학술대회 | 2005년 봄 (04/22 ~ 04/23, 여수대학교) |
권호 | 11권 1호, p.80 |
발표분야 | 고분자 |
제목 | Single-walled Carbon Nanotubes Enveloped by Dew-shaped Polystyrene: Their Electrical and Physical Properties, and Dispersion States in Both Organic Solvents and Water |
초록 | Single-walled carbon nanotubes enveloped by dew-shaped polystyrene molecules were prepared by in situ miniemulsion polymerization of styrene. They were dispersed in water in the existence of surfactants, which were used during the polymerization. After surfactants were removed, they were soluble up to 5 wt % in a good solvent of polystyrene, and showed no precipitation for 700 hrs. A film was made by coating the solution. The electrical conductivity of the film was affected by the amount of polymer encapsulating nanotubes. The electrical conductivity and storage modului were improved as the amount of polystyrene decreased. Acknowledgment. Authors would like to express their sincere thanks to KOSEF, to CAFPoly, and to the BK 21 program for their financial support. And Dr. Sun Ha Kim at the KBSI (Daegu) is thanked for taking the solid state 400 MHz NMR data. |
저자 | 함형택1, 최용석2, 지무근1, 정인재1 |
소속 | 1한국과학기술원 생명화학공학과, 2삼성종합기술원 Fuel-cell Program Team |
키워드 | Single-walled carbon nanotubes; miniemulsion polymerization; dispersion |
원문파일 | 초록 보기 |