화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 (국제협력) 우수 외국인 연구자 세션
제목 CdS nanograin sensitized Zr:Fe2O3 nanorod array for highly efficient solar-light-driven photoelectrocatalytic performance
초록 Well-defined CdS nanograins sensitized Zr:Fe2O3 nanorods with enhanced photoelectrocatalytic performance are synthesized on F-doped SnO2(FTO) using hydrothermal method. Owing predominantly to the appropriate band positions and charge collection in Zr:Fe2O3 nanorods, CdS/Zr:Fe2O3 heterostructure exhibit 1.7 times improved photocurrent density compared to Zr:Fe2O3. Unfortunately, CdS nanograins sensitized Zr:Fe2O3 nanorod arrays suffers from instability problem. Furthermore, Ni(OH)2 loading can boost the PEC performance of heterojunction and also acts as a protective layer that improves the stability of the Ni(OH)2/CdS/Zr:Fe2O3 electrode. Such enhanced PEC activity may be ascribed to the effective charge separation between CdS and Zr:Fe2O3 nanorods as well as increases the lifetime of holes due to Ni(OH)2.

This work was supported by the BK21 plus program through the National Research Foundation (NRF).
저자 MAHADIK MAHADEO ABASAHEB1, Arunprabaharan Subramanian1, 류정호2, 조민1, 장점석1
소속 1전북대, 2한국지질자원(연)
키워드 CdS nanograins; Ni(OH)2 cocatalyst; Sensitizer; CdS/Zr:Fe2O3 heterostructure
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