화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 봄 (04/07 ~ 04/09, 대전컨벤션센터)
권호 46권 1호
발표분야 콜로이드 및 분자조립 부문위원회 Ⅰ
제목 Synthesis of CH3NH3PbBr3 Core/Shell Quantum Dots  using by 3-aminopropyl(diethoxy)methylsilane for Enhanced Dispersibility
초록 Organometal halide perovskite quantum dots (PQDs) have high-purity light-emitting materials and a wide wavelength range, which can be a significant advantage in display application. However, the commercialization of QDs synthesized using halide perovskites is hindered by its low thermal stability and instability during their long-time exposure to external light sources as a major drawback. Encapsulating the QDs is one way of overcoming these drawbacks. We synthesized core/shell QDs using silica material. Here, to improve these issues, the synthesis of hydrophobic QDs@SiO2 structures through a one-step method is presented. The synthesized QDs@SiO2 obtained a maximum PLQY of 96.5 %. A shell was made to protect the core by using a hydrophobic ligand outside the QDs, and as a result, the emission of heavy metal perovskite was suppressed. QDs@SiO2 protected the decomposition of QDs in a polar environment, and PL was maintained even in a thermal environment.
저자 김진영, 김병기, 장웅식, 왕동환
소속 중앙대
키워드 halide perovskite; quantum dot; silica core/shell structure; dispersibility; stability
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