화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 에너지저장변환
제목 Control of back electron transfer by surface modification of photoanode in TiO2-based solar cells
초록 The effects of nickel nitrate as a surface modifier on the back electron transfer between photoinjected electrons and electrolyte in dye-sensitized soar cells (DSSCs) were studied. Nickel nitrate-modified TiO2 electrodes (NN-TiO2/FTO) prepared by a soaking process were applied to the photoelectrodes of DSSCs. The reference device without any modification showed a performance of 0.714V of open-circuit voltage (Voc), 17.21 mA/cm2 of short-circuit current(Jsc), and 72.64% of fill factor (FF), which led to a power conversion efficiency (PCE) of 8.93%, whereas for the device with the NN-TiO2/FTO electrode, the PCE was increased to 9.92%(Voc = 0.728 V, Jsc = 18.95 mA/cm2, and FF = 71.88%).
저자 김수빈1, 조성일1, 최근영1, 성혜경1, 김지영2, 김욱현2, 우성호2, 한윤수1
소속 1대구가톨릭대, 2대구경북과학기술원
키워드 Nickel nitrate; dye-sensitized solar cells; back electron transfer; photoelectrode
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