화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 고분자_포스터
제목 A-D-A Small Molecules based on Indacenodithieno[3,2-b]thiophene as the Donor Materials with Chromone Derivatives for Organic Solar Cells
초록 Conjugated small-molecule-donor masterials based on indacenodithieno[3,2-b]thiophene (IDTT) and the chromone derivatives, named SMD1 (without fluorine) and SMD2 (with fluorine), were synthesized for organic solar cells. The chromone derivatives as an electrone-accepting group, when combined with IDTT, can effectively form a powerful push-pull structure that induces effective ICT and enhanced optical absorption. The PCEs of the devices based on small molecule donors containing fluorine in the terminal accepting group showed higher performances. Furthermore, the PCEs of the devices containing DIO as a processing additive were dramatically decreased. The HOMO/LUMO energy levels of the SMD1 and SMD2 were -5.33/-3.56 and -5.39/-3.50 eV, respectively. The best performance based on SMD1/PC71BM and SMD2/PC71BM were 1.03% and 2.23% without the addition of DIO, respectively.
저자 Ratna dewi maduwu, 김주현, 진호철, sabrina aufar salma, 이준호, 정미진
소속 부경대
키워드 Organic solar cells; benzothiadiazole; dicyanomethylene-4H-chromene; 2; 2'-(1H-indene-1; 3(2H)-diylidene)dimalononitrile
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