화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 고분자 구조 및 물성
제목 Thermally stable Poly(vinylidene fluoride-co-trifluoroethylene) crystal lamellae ordered on PTFE substrates and their polarization characteristics in thin film capacitor
초록 Poly(vinylidene fluoride) (PVDF) and its copolymers with trifluoroethylene (TrFE) have been of a great attention in virtue of mainly low cost processibility for their potential use in non-volatile polymer memory. The basic ferroelectric polymer storage element is metal/ferroelectric polymer/metal capacitor in which a ferroelectric polymer thin film sandwiched between metal electrodes. Here, we introduced an oriented PVDF-TrFE thin films processed onto oriented PTFE substrates in the ferroelectric polymer capacitor. Epitaxial growth of PVDF-TrFE on PTFE with frictionally rubbing method was characterized with Transmission Electron Microscopy and X-ray diffraction. We observed that the oriented lamellae PVDF-TrFE maintained their morphology even after high temperature annealing upto 200°C, which is above melting temperature. In order to see the effect of oriented film on its ferroelectricity, we fabricated polymer capacitor and measured polarization characteristics.
저자 박연정1, Bernard Lotz2, 박철민1
소속 1연세대, 2Institut Charles Sadron
키워드 ferroelectric polarization; oriented PTFE substrates; epitaxy; crystal orientation
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