초록 |
Reaction kinetic model is important to design process and to find the optimal condition of reaction. In this study, we derive reaction kinetics of formic acid from CO2 hydrogenation using triethylamine solution and Ru-based heterogeneous catalyst with hydrogen. Using the experimental data and prior study, we estimate the reaction mechanism and the rate-determining step, needed to make Langmuir-Hinshelwood equation. To estimate parameters in kinetics model, the levenberg-marquardt algorithm was used. |