학회 |
한국화학공학회 |
학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
권호 |
21권 1호, p.1212 |
발표분야 |
환경 |
제목 |
Polyvinyl alcohol (PVA) with lithium ion sieves (LIS): A novel reusable lithium adsorbent foam prepared via cryo-desiccation and chemical cross-linking |
초록 |
Composite polyvinyl alcohol (PVA) with H1.6Mn1.6O4 (HMO) foams were produced via cryo-desiccation method as lithium (Li+) adsorbents. SEM-EDS and FE-EPMA revealed homogenous HMO distribution in the 3D network of the foam. Hydrophilicty of the PVA-HMO foams facilitated good contact between the Li+ solution and the adsorbents, minimizing Li+ adsorption loss of the foams relative to the HMO powder. Adsorption performance improved at high HMO loading of 250%. Further increase in loading (300%) resulted in poor mechanical stability. In a simulated seawater, PVA-HMO foam preferentially adsorbed Li+ over other cations. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science, ICT & Future Planning (No. 2012R1A2A1A01009683) and the Ministry of Education (No. 2009-0093816). |
저자 |
LIMJUCO LAWRENCE1, Grace M. Nisola2, Eleazer L. Vivas3, Myoung Jun Park1, Hokyong Shon2, Neha Mittal3, Seong-Poong Lee1, Jeong Gil Seo2, 정욱진3
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소속 |
1Department of Energy Science and Technology(DEST), 2Energy and Environment Fusion Technology Center (E2FTC), 3Myongji Univ. |
키워드 |
Polyvinylalcohol; adsorption; ion sieve; lithium recovery; composite foam
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