| 학회 |
한국공업화학회 |
| 학술대회 |
2007년 가을 (11/02 ~ 11/03, 한경대학교) |
| 권호 |
11권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Preparation of Hydrofluoroether Using Hydroakoxylation of Fluoroalcohol and Fluoroolefin |
| 초록 |
Hydrofluoroethers (HFEs) are being used as third generation replacements to chlorofluorocarbons (CFCs), hydrofluorochlorocarbons (HCFCs) and perfluorocarbons (PFCs) because of their nearly zero stratospheric ozone depletion and relatively low global warming potential. In this study. we investigated hydroalkoxylation reaction between alcohol or fluoroalcohol and hexafluoropropene using fluoride salt as catalyst to make fluorinated ethers like CF3CHFCF2OCH2CF3, CF3CHFCF2OCF2CH2CF3, CF3CHFCF2OCH2CHFCH3, CF3CHFCF2OCF2CHFCHFCF3 and CF3CHFCF2OCH(CF3). Among the fluoride catalyst tested, potassium salt showed the best activity in yield and selectivity. IR study showed fluoride anion interacts with hydroxyl group of alcohol to weaken 0-H bond, which seems to promote addition of alcohol to hexafluoropropene. |
| 저자 |
Debby Natalia1, 이현주1, 김훈식2, 김홍곤1, 오지희1, 김승욱3
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| 소속 |
1한국과학기술(연), 2경희대, 3고려대 |
| 키워드 |
Hydrofluoeoether; Hydroalkoxylation
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| E-Mail |
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