화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터)
권호 14권 2호
발표분야 환경.에너지
제목 Direct Oxidation of Methane in Ni/SDC Anode for Solid Oxide Fuel Cell
초록 SOFCs can operate directly with hydrocarbon fuel without the need of external reforming process.However, hydrocarbon has less electrochemical activity than hydrogen in conventional Ni/YSZ anode.Therefore, a better performance electrochemical catalyst for hydrocarbon oxidation is necessary for practical application purpose.In this study, a NiO (70wt%)/Sm0.2Ce0.8O1.9 anode was investigated for direct electrochemical oxidation ofCH4.YSZ (8 mol% yttria) electrolyte supported single cells with Ni/SDC and Ni/YSZ were investigated in H2 and CH4.Compared with the Ni/YSZ anode, the Ni/SDC was exhibited higherOCV and lower anode polarization resistance leading to higher performance.Degradation of the cell performance was much lower in Ni/SDC anode for long-term test.
저자 윤정우, 윤성필, 남석우, 한종희, 박상균, 김희수
소속 한국과학기술(연)
키워드 Solid oxide fuel cell; methane; direct electrochemical oxidation; Samaria doped ceria
E-Mail