| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Reduction responsive microsphere composed of alginate, propylene sulfide, and calcium chloride |
| 초록 |
Alginate-propylene sulfide (ALG-PS) were polymerized by ring opening. As a result, the thiol group was introduced into alginate. Quantitative analysis of the synthesized ALG-PS was analyzed through 1HNMR. The ALG-PS was crosslinked with the calcium chloride and microsphere was prepared by W/O emulsion method. The morphology of alginate-propylene sulfide-Ca2+ chloride (ALG-PS-Ca2+) microsphere was observed on scanning electron microscope. The qualitative analysis of sulfur content of ALG-PS-Ca2+ microsphere was examined by energy-dispersive X-ray spectroscopy. The prepared ALG-PS-Ca2+ microsphere was added to dimethyl sulfoxide to oxidize the thiol group of the ALG-PS-Ca2+ microsphere to disulfide bond. This has led to the introduction of reduction-responsive properties in ALG-PS-Ca2+ microsphere. The formed disulfide bond of ALG-PS-Ca2+ microsphere was observed through the raman spectrometer. |
| 저자 |
김태훈, 김진철
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| 소속 |
강원대 |
| 키워드 |
Reduction-responsive; ring opening polymerization; oxidation; W/O emulsion; microsphere
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| E-Mail |
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