화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1972
발표분야 재료
제목 Preparartion and Catalytic Performance of Functionalized Mesoporous Silica/Ceria-Silica Composites
초록 We present the preparation method and characterization of various mesoporous silica/ceria-silica composites using cerium hydroxide (or cerium nitrate) and TEOS precursors in the presence of a cationic surfactant under basic conditions. Mn-doped mesoporous silica/ceria-silica was also prepared using sol-gel method. Ce content (Ce/Si) was up to 0.5 confirmed by ICP methods maintaining hexagonal mesostructure. In case Manganese was incorporated inside the composites, the Ce content was up to 0.3. Catalytic performance of ceria-silica and Mn-doped ceria-silica composites were investigated for oxidation and esterification reactions. The results showed catalytic performance is quite effective in solvent-less and mild temperature conditions.      
저자 조은범1, Pal Nabanita2, 김덕준3
소속 1서울과학기술대, 2Saha Institute of Nuclear Physics, 3성균관대
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