화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.1999
발표분야 에너지
제목 Preparation and electrocatalytic activity of Pt-Ru catalysts deposited on branched polyer modified graphene sheets
초록 In this study, we used cationic polymers to modify the surface of modified graphene oxide (GO) which have a good dispersion in various solutions and an enhanced electrochemical sensitivity with electrolytes. The interlayer distance of graphene sheets was also increased by modifier agent. The branched polyethyleneimine (BPEI), one kind of ionic polymer, was used for modifier agent and GO was prepared by modified Hummers method. In addition, the electrochemical analysis was carried by cyclic voltammetry (CV). CV was operated at room temperature and electrolytes were used 1.0M methanol and 0.5M sulfuric acid. The transmission electron microscopy (TEM) and scanning electron microscopy (SEM) were used to observe particle size and morphology of Pt-Ru electrocatalysts, respectively. Furthermore, microstructure and metal components on graphene sheet were confirmed by x-ray diffraction (XRD) and x-ray protoelectron spectroscopy (XPS), respectively.
저자 박재영, 김 석
소속 부산대
키워드 modified graphene oxide; branched PEI; nanocomposite
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