학회 |
한국공업화학회 |
학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
권호 |
19권 1호 |
발표분야 |
고분자_포스터 |
제목 |
Supercapacitive properties of electrodeposited polyaniline electrode in acrylic gel polymer electrolytes |
초록 |
Polyaniline (PAn) electrode for a supercapacitor is prepared by electrodepositing on a platinum substrate. Its supercapacitive properties are characterized after adopting acrylic gel polymer electrolytes, such as poly(acrylic acid) (PAA), potassium polyacrylate (PAAK), and poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS). The electrodeposited PAn (ePAn) exhibits a network structure compactly connected with particles or particle aggregates to yield a porous morphology with an average pore size of 4 μm. The cyclic voltammogram of the ePAn electrode shows redox pair peaks on both cathodic (around 0.2 V) and anodic scans (around 0.1 V vs. Ag/AgCl) at low scan rates, but the redox peak potentials shift to give a higher potential difference at high scan rates, implying higher polarization. Except for the H2O/PAMPS electrolyte, the ePAn supercapacitor that adopts the acrylic gel polymer electrolytes exhibits comparable specific capacitance of 400–500 F g−1, even at high scan rates, due to specific interactions between the H2SO4 solvent molecules and acrylic polymers. |
저자 |
이해수1, LOUIS HAMENU1, LATIFATUMOHAMMED1, Hu Mengyang1, Alfred Madzamuse1, Ji Hyun Nam1, Kwang Man Kim2, Jang Myoun Ko1
|
소속 |
1Hanbat National Univ., 2Electronics and Telecommunications Research Institute |
키워드 |
Polyaniline; Electrodeposition; Acrylic gel polymer electrolyte; Supercapacitor
|
E-Mail |
|