화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 콜로이드 및 분자조립 부문위원회 I
제목 Eutectic Crystallization of Binary Colloidal Fluids in Double-Emulsion Drops for Dual Photonic Stopbands
초록 Colloidal crystals show structural colors through selective reflection of light at stopband. We can fabricate photonic capsules with colloidal crystals by microfluidic devices. When polymer chains and particles are present in the medium, the polymer chains induce depletion-attraction between particles. Even charged colloidal particles are crystallized in the medium by depletion-attraction force. Here, photonic capsules which display mixed structural color is achieved by independent crystallization of polystyrene (PS) nanoparticles with different sizes via depletion-induced phase separation. Crystallization of colloids occurs during the concentration process of capsules that contain PS nanoparticles and depletant. We crystallize two types of particles in groups by controlling the attraction force. In addition, the degree of color mixing is controlled by the sizes of each crystallite, which are controllable with the rate of concentration.
저자 김영건, 박상혁, 김신현
소속 한국과학기술원
키워드 colloidal crystals; microcapsules; depletion attraction
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