화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-고분자
제목 Alternating Copolymer Based on Phenazine with Di-Fluorine and Thiophene Derivative for OPVs
초록 Energy is global issue in these days, and solar energies are studied a lot. Polymer solar cells are made of polymers that have a D-A copolymer structure. D unit of the polymer is BenzoDiTionylThiophene(BDTT). A unit of polymer is Di-Fluorinated Phenazine. This study is the efficiency change according to switching of alkyl chain that one is linear alkyl chain (Dodecyl) the other is bulky alkyl chain(2-ethylhexyl, 2-butyloctyl). Among these 3 type of polymers, 2-Butyloctyl Di-Fluorinated Phenazine has best performance that 5.28% of PCE. The Dodecyl chain has high cohesive attraction. So it causes low dispersion. Also the polymer with ethyl-hexyl chain causes same problem. Butyloctyl has appropriate size of crystal to work in PSCs.
저자 안상훈, 진영읍, 이근대, 박성수, 이원기
소속 부경대
키워드 OSC; OPV; PSC
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