| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
| 권호 |
42권 2호 |
| 발표분야 |
고분자가공/복합재료 |
| 제목 |
Functionalization multiwalled carbon nanotubes in deep eutectic solvent via Diels-Alder click reaction |
| 초록 |
Deep eutectic solvents (DES), a new type of cost-effective ionic liquid analogues, has been utilized to develop a novel and efficient method for direct functionalization multiwalled carbon nanotubes (MWCNT) via Diels-Alder (DA) click reaction. First, furfuryl amine as a DA reactive groups were incorporated in to the chain of poly(styrene-alt-maleic anhydride) through ring-opening reaction. Then, the polymer was directly grafted on the surface of untreated MWCNT in choline : ethylene glycol (Chl:E) based DES without any catalyst. The successful functionalization of the polymer on MWCNT was confirmed by Raman spectroscopy, TGA, FT-IR and TEM analysis. It is shown the reaction proceeded in a very rapid fashion (within an hour) and the use of DES significantly improved the grafting density with three times higher as compared with the reaction in water. |
| 저자 |
임권택, Cuong M.Q. Le, Sabina Aufar Salma, Xuan Thang Cao, 김동우
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| 소속 |
부경대 |
| 키워드 |
MWCNT; Ionic Liquid; Diels-Alder Click Reaction; co-Polymerization
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| E-Mail |
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