| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Novel D-π-A structured Zn(II)-porphyrin Dyes Containing Bulky Alkoxy Substituted Fluorene Derivatives as an Electron Donor Group for Highly Efficient Dye- sensitized Solar Cell |
| 초록 |
The iodide/triiodide redox shuttle has limited the efficiencies accessible in dye-sensitized solar cells. Here, we report dye-sensitized solar cells that incorporate a Co(II/III)tris(bipyridyl)–based redox electrolyte in conjunction with newly developed D-π-A structured Zn(II)-porphyrin dyes containing bulky alkoxy substituted fluorene derivatives as an electron donor group. The specific molecular design of the Zn(II)-porphyrin dyes greatly retards the charge recombination from the conduction band of TiO2 film to the oxidized cobalt mediator, which enables attainment of high open-circuit voltage associated with high energy conversion efficiency. |
| 저자 |
강민수, 최인택, 김연욱, 김환규
|
| 소속 |
고려대 |
| 키워드 |
DSSC; Cobalt; electrolyte; Voc; open-circuit voltage; porphyrin; dye
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| E-Mail |
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