화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 에너지저장변환_포스터
제목 Stabilization of Cathode-Electrolyte Interface in a High-Voltage Lithium-ion Battery
초록 Li-rich and Mn-rich layered oxide cathode material is known to deliver high specific capacities ≥ 250 mAhg−1 on the high-voltage operation above 4.6 V vs. Li/Li+ by de-intercalating more number of Li+ ion. This point makes this material as a promising cathode active material for advanced high-energy density Li-ion batteries. The limited anodic instability of conventional carbonate-based organic electrolytes above 4.2 V vs. Li/Li+ however makes the attainment of high-capacity difficult. To mitigate the anodic instability problem of conventional electrolyte, we have been developing new high-voltage electrolyte components to stabilize high-voltage interface between Li-rich layered oxide cathode and electrolyte. Studies of high-voltage electrochemical processes and cathode-electrolyte interfacial phenomena and their relations to cycling performance would be discussed.
저자 PHAM QUANG HIEU1, Hee-Yeol Lee1, Young-Gil Kwon2, Eui-Hyeong Hwang3, 송승완2
소속 1Chungnam National Univ., 2Leechem Co., 3Ltd
키워드 Lithium Batteries; High-Voltage Additive; SEI layer
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