학회 |
한국고분자학회 |
학술대회 |
2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터) |
권호 |
44권 2호 |
발표분야 |
분자전자 부문위원회 II |
제목 |
Synthesis of Trifluorosulfonyl Substituted Iridium Complexes for Blue Phosphorescence |
초록 |
For color-pure phosphorescence organic light emitting diodes, we synthesized the trifluoromethyl sulfonyl substituted ligand and SOCF3pic and SOCF3mpic as two new blue Iridium complexes. The SOCF3pic and SOCF3mpic complexes exhibited identical photophysical and thermal stabilities while the HOMO energy levels of two Iridium complexes slightly dissimilar to be −5.84 eV for SOCF3pic and −5.74 eV for SOCF3mpic, each material. The device with the SOCF3mpic dopant showed higher device efficiencies of 7.17 cd/A and 3.7% compared to that with the SOCF3pic dopant (4.03 cd/A and 2.78%). Two-dimensional GIXD picture of be dotted X-ray intensity from surface to full depth for SOCF3pic-doped and SOCF3mpic-doped TCTA:4PTPS films were distinct featured for preferential orientation along the out-of-plane direction. |
저자 |
김지현1, 하연희1, 김윤희1, 권순기1, 정성준2, 손선영2, 한승훈1, 김봉곤1, 안형주2
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소속 |
1경상대, 2포항공대 |
키워드 |
oled; Blue phosphorescence; Iridium complex
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E-Mail |
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