화학공학소재연구정보센터
학회 한국재료학회
학술대회 2020년 가을 (11/18 ~ 11/20, 휘닉스 제주 섭지코지)
권호 26권 1호
발표분야 E. 환경/센서 재료 분과
제목 Theoretical and experimental studies of mono- and bridged-BODIPY derivatives: Synthesis and photophysical properties
초록 Boron dipyrromethenes (BODIPYs) usually have good photophysical properties such as high molar extinction coefficients, good fluorescent quantum yields, negligible triplet state formation, narrow emission bandwidths with high peak intensities, and excellent thermal/photochemical stabilities. Various BODIPY derivatives can be synthesized for different applications by the structural modification of the boron-dipyrrin core or by making their dimers and oligomers. In this work, we introduce synthesis of monomeric and dimeric BODIPYs with different alkyl substituents. In addition, we investigated their photophysical properties such as absorption, emission and fluorescence lifetime. Finally, we did ab initio calculations to elucidate their structure and molecular orbital.
저자 김남두1, 정가람2, 배세원3
소속 1공주대, 2한국생산기술(연), 3성균관대
키워드 BODIPY; Organic Synthesis; Ab initio calculation; FLIM; UV-VIS; FLuorescence
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