| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
| 권호 | 25권 2호, p.1646 |
| 발표분야 | 에너지 환경 (Energy and Environment) |
| 제목 | A comparative study on the activity of Cu-CeO2-ZrO2 catalyst for LT-WGS depending upon the CeO2/ZrO2 ratio |
| 초록 | A comparative study on cubic Cu-Ce0.8Zr0.2O2 and tetragonal Cu-Ce0.2Zr0.8O2 catalysts have been carried out in the Low Temperature Water Gas Shift (LT–WGS) reaction. The catalysts were prepared by the first co-precipitation / digestion method. The physicochemical properties of catalysts prepared were examined by BET, XRD, and H2-TPR. The cubic Cu–Ce0.8Zr0.2O2 catalyst shows higher CO conversion (XCO＞ 60% at 400oC) than tetragonal Cu-Ce0.2Zr0.8O2 catalyst at the high Gas Hourly Space Velocity (GHSV) of 72,152 h-1. The high catalytic activity of the Cu-Ce0.8Zr0.2O2 is mainly related to the enhanced oxygen mobility and high Cu dispersion resulting from large amount of defect oxygen. In addition, cubic Cu-Ce0.8Zr0.2O2 catalyst exhibits a stable activity at 320 oC for 25 h resulting from a strong resistance against sintering. Acknowledgments: This research was supported by the Korea Ministry of Environment as Waste to Energy-Recycling Human Resource Development Project (YL-WE-19-001). |
| 저자 | 변희주, 정창훈, 정대운 |
| 소속 | 창원대 |
| 키워드 | 에너지 환경 |
| 원문파일 | 초록 보기 |
